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OPTIMIZATION OF BIODIESEL PRODUCTION FROM YELLOW OLEANDER AND CASTOR OILS AND STUDIES OF THEIR FUEL PROPERTIES

Abstract

The optimization of biodiesel production from two non-edible oils and studies of their fuel and biodegradability properties was carried out. The two oil feedstocks (Yellow oleander and Castor oils) were extracted from their seeds using an oil expeller and their physicochemical properties such as iodine value, moisture content, saponification value, acid value, viscosity, specific gravity and refractive index were determined. Most of these properties were within the acceptable limit of American Standard Testing Method (ASTM). The methyl esters were optimized using methanol as solvent and by varying conditions like reaction temperature, reaction time, type and concentration of catalyst, molar ratio of methanol and oil. For maximum bio diesel production, the transesterification reaction showed that the concentration of alkali catalyst was 0.8 % sodium hydroxide, 0.33 %v/v alcohol/oil ratio, 1 hr reaction time, 60 0C temperature and excess alcohol 150 %v/v. Optimized parameters for production of biodiesel through base catalyzed transesterification gave maximum yield of 96 % and 98 % for yellow oleander and castor oil respectively. The Yellow Oleander Methyl Ester (YOME) and Castor Oil Methyl Ester (COME) and their diesel blends were comparatively analysed for fuel properties such as flash point, relative density, kinematic viscosity, calorific value, distillation, sulphur, phosphorous, water content, cetane number and acid number . The methyl ester of yellow oleander was found to have properties closer to ASTM D 6751 fuel specifications than that of castor oil. It is further observed from the results that the biodiesel from yellow oleander and castor oil are environmentally friendly, such that after spillage, it will take about 28 days for them to have biodegradability of 82.4 and 87.3 for YOME and COME respectively. This is an advantage over petro-diesel which was found to have biodegradability of 25.29 in 28 days.

3,000.00

Description

CHAPTER ONE

1.0 INTRODUCTION

The world energy sector depends on the petroleum, coal and natural gas reservoirs to fulfill its energy requirements (Meher et al., 2006). Nigeria is traditionally an energy-deficient country which exports above 70% of its crude oil production. The country is dependent upon import of petroleum products to sustain its growth. Diesel fuel plays an essential function in the industrial economy of Nigeria. The fuel is used in heavy trucks, city transport buses, electric generators, farm equipment etc. (Anjana, 2000). However, diesel engine also emits various forms of pollutants into the environment which can endanger human health and damage the ecological environment (Antolin et a.l, 2002). It is therefore essential that the world extend its interest towards new sources of energy. A relatively new alternative that is currently booming worldwide is fuel obtained from renewable resources or biofuel. Biofuels are well suited for decentralized development i.e can be utilised to meet the needs for social and economic progress, especially in rural communities where fossil fuels may be difficult or expensive to obtain (Nwafor and Nwafor, 2000; Ezeanyananso et al., 2010).

Amongst the various alternative fuels which could match the combustion features of diesel oil and can be easily adapted for use in existing engine technologies with or without any major modifications is biodiesel. Biodiesel fuel produced from vegetable oils (both edible and non edible) or animal fats is one of the promising possible sources that can be substituted for conventional diesel fuel and produces favourable effects on the environment. Biodiesel is recommended for use as a substitute for petroleum diesel

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mainly because it is a renewable, domestic resource with an environmentally friendly emission profile and is readily available and biodegradable (Zhang et al., 2003).

The research and use of biodiesel fuel as an alternative started in the 1980?s and the reason was the diesel crisis caused by the reduction of petroleum production by the Organization of Petroleum Exporting Countries (OPEC) and the resultant price hike. The biodiesel produced from locally available resources offer a great promise for future application in Nigeria as it can help in attaining much needed energy security and being environment friendly, will help to conform to stricter emission norms (Ezeanyananso, 2010).

Castor plant (Ricininus communis)

Ricinus communis (Plate I) is a species that belongs to the Euphorbiaceae family and it is commonly known as castor oil plant, and Palma christi. Castor oil is possibly the plant oil industry?s most underappreciated asset. It is one of the most versatile of plant oils, being used in over ten diverse industries.

Owing to its unique chemical composition and structure, castor oil can be used as the starting material for producing a wide range of end-products such as biodiesel, lubricants and greases, coatings, personal care and detergent, surfactants, oleo chemicals e.t.c. Compared to many other crops, castor crop requires relatively fewer inputs such as water, fertilizers and pesticides. The crop can also be grown on marginal land, thus providing an excellent opportunity for many regions of the world to utilize their land resources more productively (Dokwadanyi, 2011). The plant prefers well-drained moisture relative clay or sandy loan in full sun requires a rich soil and day time temperature above 20oC for

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